Inside Cover: Modular Synthesis of a Tridecasaccharide Motif of <i>Bacteroides vulgatus</i> Lipopolysaccharides against Inflammatory Bowel Diseases through an Orthogonal One‐Pot Glycosylation Strategy (Angew. Chem. Int. Ed. 22/2023)

Lipopolysaccharides from Bacteroides vulgatus represent interesting targets for the treatment of inflammatory bowel diseases. In their Research Article (e202301351), Guozhi Xiao and co-workers accomplished first synthesis a tridecasaccharide motif lipopolysaccharides by strategy involving orthogonal one-pot glycosylation reactions based on glycosyl ortho-(1-phenylvinyl)benzoates, which precluded issues such as aglycone transfer unpleasant odor thioglycoside-based glycosylation.